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<h1 id="firstHeading" class="firstHeading" lang="en">Cb05tump ae6 v5.1 mech.def</h1>			<div id="bodyContent" class="mw-body-content">
				<div id="siteSub" class="noprint">From CMASWIKI</div>				<div id="contentSub"></div>
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				<div id="mw-content-text" lang="en" dir="ltr" class="mw-content-ltr"><div class="mw-parser-output"><p>cb05tump contains all the gas-phase reactions of <a href="../index.php/Cb05tucl_ae6_v5.1_mech.def" title="Cb05tucl ae6 v5.1 mech.def">cb05tucl_ae6_aq</a> plus these <b>additional</b> reactions:
</p><p><br />
</p>
<ul><li>For rate constants with the form A/&lt;<i>PHOT</i>&gt;, k equals A times the photolysis rates, <i>PHOT</i>.</li></ul>
<ul><li>Units of rate constants give reactions rates in units of molecules cm<sup>-3</sup> s<sup>-1</sup>. Note that T equals air temperature in degrees K in the below table.</li></ul>
<p>Check the <a href="../index.php/Cb05tump_Additional_Species_Table" title="Cb05tump Additional Species Table">species table</a> for the reactants and products added to the <a href="../index.php/Cb05tucl_species_table" title="Cb05tucl species table">cb05tucl reactant and products.</a>
</p>
<table class="wikitable">

<tbody><tr>
<th>Label
</th>
<th>Reaction
</th>
<th>Rate Const
</th>
<th>Notes
</th>
<th>Reference
</th></tr>
<tr>
<td>&lt;T01&gt;</td>
<td>FORM_PRIMARY + OH = OH</td>
<td>9.0E-12</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T02&gt;</td>
<td>FORM_PRIMARY + NO3 = NO3</td>
<td>5.8E-16</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T03&gt;</td>
<td>FORM_PRIMARY + O = O</td>
<td>3.4E-11*exp<sup>(-1600/T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T04&gt;</td>
<td>FORM_PRIMARY =</td>
<td>1.0/&lt;HCHO_R_SAPRC99&gt;</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T05&gt;</td>
<td>FORM_PRIMARY =</td>
<td>1.0/&lt;HCHO_M_SAPRC99&gt;</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;TCL1&gt;</td>
<td>FORM_PRIMARY + CL = CL</td>
<td>8.2E-11*exp<sup>(-34/T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T06&gt;</td>
<td>ALD2_PRIMARY + OH = OH</td>
<td>5.6E-12*exp<sup>(270/T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T07&gt;</td>
<td>ALD2_PRIMARY + NO3 = NO3</td>
<td>1.4E-12*exp<sup>(-1900/T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T08&gt;</td>
<td>ALD2_PRIMARY + O = O</td>
<td>1.8E-11*exp<sup>(-1100/T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T09&gt;</td>
<td>ALD2_PRIMARY =</td>
<td>1.0/&lt;CCHO_R_SAPRC99&gt;</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;TCL2&gt;</td>
<td>ALD2_PRIMARY + CL = CL</td>
<td>7.9E-11</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T10&gt;</td>
<td>BUTADIENE13 + OH = OH + 0.58*ACROLEIN</td>
<td>1.4E-11*exp<sup>(424./T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T11&gt;</td>
<td>BUTADIENE13 + O3 = O3 + 0.52*ACROLEIN</td>
<td>8.2E-15*exp<sup>(-2070./T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T12&gt;</td>
<td>BUTADIENE13 + NO3 = NO3 + 0.045*ACROLEIN</td>
<td>1.79E-13</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;TCL3&gt;</td>
<td>BUTADIENE13 + CL = CL + 0.58*ACROLEIN</td>
<td>2.51E-10</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T14&gt;</td>
<td>ACROLEIN_PRIMARY + OH = OH</td>
<td>2.0E-11</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T15&gt;</td>
<td>ACROLEIN_PRIMARY + O3 = O3</td>
<td>2.61E-19</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T16&gt;</td>
<td>ACROLEIN_PRIMARY + NO3 = NO3</td>
<td>1.7E-11*exp<sup>(-3131./T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T17&gt;</td>
<td>ACROLEIN_PRIMARY =</td>
<td>1.0/&lt;ACROLEIN_SAPRC99&gt;</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;TCL4&gt;</td>
<td>ACROLEIN_PRIMARY + CL = CL</td>
<td>2.37E-10</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T18&gt;</td>
<td>ACROLEIN + OH = OH</td>
<td>2.0E-11</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T19&gt;</td>
<td>ACROLEIN + O3 = O3</td>
<td>2.61E-19</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T20&gt;</td>
<td>ACROLEIN + NO3 = NO3</td>
<td>1.7E-11*exp<sup>(-3131./T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T21&gt;</td>
<td>ACROLEIN =</td>
<td>1.0/&lt;ACROLEIN_SAPRC99&gt;</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;TCL5&gt;</td>
<td>ACROLEIN + CL = CL</td>
<td>2.37E-10</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T22&gt;</td>
<td>TOLU + OH = OH</td>
<td>1.8E-12*exp<sup>(355./T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;TCL6&gt;</td>
<td>TOLU + CL = CL</td>
<td>6.1E-11</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T23&gt;</td>
<td>MXYL + OH = OH</td>
<td>1.7E-11*exp<sup>(116./T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;TCL7&gt;</td>
<td>MXYL + CL = CL</td>
<td>1.4E-10</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T24&gt;</td>
<td>OXYL + OH = OH</td>
<td>1.22E-11</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;TCL8&gt;</td>
<td>OXYL + CL = CL</td>
<td>1.5E-10</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T25&gt;</td>
<td>PXYL + OH = OH</td>
<td>1.3E-11</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;TCL9&gt;</td>
<td>PXYL + CL = CL</td>
<td>1.5E-10</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T26&gt;</td>
<td>APIN + O = O</td>
<td>2.79E-11</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T27&gt;</td>
<td>APIN + OH = OH</td>
<td>1.2E-11*exp<sup>(440./T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T28&gt;</td>
<td>APIN + O3 = O3</td>
<td>6.3E-16*exp<sup>(-580./T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T29&gt;</td>
<td>APIN + NO3 = NO3</td>
<td>1.2E-12*exp<sup>(490./T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;TCL10&gt;</td>
<td>APIN + CL = CL</td>
<td>4.7E-10</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T30&gt;</td>
<td>BPIN + O = O</td>
<td>2.81E-11</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T31&gt;</td>
<td>BPIN + OH = OH</td>
<td>7.51E-11</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T32&gt;</td>
<td>BPIN + O3 = O3</td>
<td>1.74E-15*exp<sup>(-1260./T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;T33&gt;</td>
<td>BPIN + NO3 = NO3</td>
<td>2.81E-11</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;TCL11&gt;</td>
<td>BPIN + CL = CL</td>
<td>5.3E-10</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;HG1&gt;</td>
<td>HG + O3 = 0.5*HGIIAER + 0.5*HGIIGAS + O3</td>
<td>2.11E-18*exp<sup>(-1256.5/T)</sup></td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;HG2&gt;</td>
<td>HG + CL2 = HGIIGAS + CL2</td>
<td>2.6E-18</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;HG3&gt;</td>
<td>HG + H2O2 = HGIIGAS + H2O2</td>
<td>8.5E-19</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;HG4&gt;</td>
<td>HG + OH = 0.5*HGIIAER + 0.5*HGIIGAS + OH</td>
<td>7.7E-14</td>
<td></td>
<td>
</td></tr>
<tr>
<td>&lt;HG5&gt;</td>
<td>HG + CL + M = 0.5*HG + 0.5*HGIIGAS + M + CL</td>
<td>2.25E-33*exp<sup>(-680.0/T)</sup></td>
<td></td>
<td>
</td></tr>
</tbody></table>

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